Question 1 :
The $$IUPAC$$ name of $$\displaystyle K_{4}\left [ Fe\left ( CN \right )_{6} \right ]$$ is:
Question 2 :
When $$ CuSO_4 $$ solution is added to $$ K_4[Fe(CN)_6] $$ the formula of the product formed is
Question 9 :
A complex whose IUPAC name is not correctly written is :<br>
Question 10 :
A solution containing $$2.675$$g of $$CoCl_3\cdot 6NH_3$$ (molar mass $$=267.5$$ g $$mol^{-1}$$) is passed through a cation exchanger. The chloride ions obtained in solution were treated with excess of $$AgNO_3$$ to give $$4.78$$g of $$AgCl$$(molar mass$$=143.5$$g $$mol^{-1}$$). The formula of the complex is?
Question 11 :
A complex compound of cobalt has molecular formula containing five $$NH_{3}$$ molecules, one $$NO_{2}$$ group and two $$Cl$$ atoms for one $$Co$$ atom. One mole of this compound produces three moles of ions in aqueous solution. On reacting with an excess of $$AgNO_{3}$$ solution, two moles of $$AgCl$$ get precipitated. The ionic formula of the compound is:<br/>
Question 12 :
The IUPAC name for the complex $$\displaystyle \left [ Co\left ( NH_{3} \right )_{5}\left ( NO_{2} \right ) \right ]Cl_{2}$$ is:
Question 14 :
Which of the following is correct IUPAC name of any complex compound?
Question 17 :
When $$H_2O$$ is shaken with an acidified solution of $$K_2Cr_2O_7$$ in the presence of ether, the ethereal layer turns blue due to the formation of :
Question 18 :
The IUPAC name for the coordination compound $$\displaystyle Ba\left [ BrF_{4} \right ]_{2}$$ is:
Question 19 :
One mole of the complex compound $$Co(NH_3)_5Cl_3$$ gives $$3$$ moles of ions on dissolution in water. One mole of the same complex reacts with two moles of $$AgNO_3$$ solution to yield two moles of $$AgCl(s)$$. The structure of the complex is?
Question 20 :
A pink coloured salt turns blue on heating. The presence of which cation is most likely?
Question 23 :
Which of the following statements are true regarding Werner's theory are true?<br/>$$( 1 )$$ Ligands are connected to the metal ions by covalent bonds<br/>$$( 2 )$$ Secondary valencies have directional properties<br/>$$( 3 )$$ Secondary valencies are non- ionizable<br/>
Question 26 : <div>The Alsatian-Swiss chemist Alfred Werner pioneered the field of coordination chemistry in the late nineteenth century. At that time, a number of compounds of cobalt (III) chloride with ammonia were known, with general formula $$CoCl_3.xNH_3$$ $$x=3\ to\ 6$$<br/>Treatment of these compounds with aqueous HCl acid did not remove the ammonia. However, treatment of the compounds with excess of $$AgNO_3$$ at 273 K gave white precipitate of AgCl in varying ratio depending on the structure. Also each complex had electrical conductivity of varying nature.</div><div> <br/></div><div>There is no reaction of the compound with aqueous HCl indicating that there is no free $$NH_3$$. Thus, $$NH_3$$ ligand is bonded to cobalt(III) by________ .<br/></div>
Question 27 :
Which of the following contains one unpaired electron in the 4p orbitals?<br/>
Question 30 :
In the metal carbonyls of the general formula $$M{ \left( CO \right)  }_{ x }$$ where M = metal, x = 4, EAN rule satisfied for atomic number of M equal to :
Question 32 :
Select the correct I.U.P.A.C name for $$[Ti (\pi - C_5H_5)_2(\sigma - C_5H_5)_2]$$.<br/>
Question 37 :
Which of the following primary and secondary valencies are not correctly marked against the compound?
Question 39 :
Select the correct I.U.P.A.C name for $$Mo(\sigma - C_3H_5)(\pi - C_5H_5)(CO)_3$$ :<br>
Question 40 :
Which of the following compounds have been named correctly according to IUPAC rules: <br/>(a)$$[Cr(NH_3)_5CO_3]Cl$$   -  Pentamminecarbonatochromium (III) chloride<br/>(b)$$[Co(NH_3)_5ONO]Cl_2$$  -  Pentammine-O-nitritocobalt (III) chloride<br/>(c)$$K_3[Cr(CN)_6]$$ -  Potassium hexacyanochromate(III)<br/>(d)$$[Co(NH_3)_6]Cl_3$$  - Hexamminecobalt (III) chloride<br/>
Question 44 :
The complex ion in the compound $$\displaystyle Cs\left [ MnF_{4}\left ( H_{2}O \right )_{2} \right ]$$ is octahedral and high spin. The name of the compound is :
