Page 1 : TIQERDA (Syllabus), , ware fee & yerya agra, ai.cest. cares faer-1, , BEM. - 2020 & UIGUDANGAR (w.e.f. 2021-22), ad.caeh. ax-4, , Unit | (Molecular Polarity and Weak Chemical Forces), Introdveton to indian ancient Chemistry and contribution of indian Chemists in cantext tothe holistic development of madern science and, technology, should be included underContinues Evaluation (CE)., , Resonance and resonance energy, formal charge, Van der Waals forces, lon-dipole forces, dipole-dipole interactions, induced dipole, interaction, dipole moment and molecular Structure (Diatomic and polyatomic molecules), Percentage ionic character from dipole, ‘moment, polarizing power and polarizability. Fajan's ules and consequences of polarization . Hydrogen bonding, van der Waals forces,, Jon-dipole forces, dipole-dipole interactions, induced dipole interaction., , Unit I (Simple Bonding Theories of Molecules), , ‘Atomic orbitals, Aufbau principle, multiple bonding (and x bond approachJand bond lengths, the valence bond theory (VBT), Concept, cof hybridization, hybrid orbitals and molecular geometry, Bent'srule,Valence Shell Electron Pair Repulsion theory (VSEPR), shapes of, the following simple molecules and ions containing one pairsand bond pairs of electrons: HO, NH, PCls, SFe, SF, ClFy 5 .and HO", Molecular Orbital Theory (MOT). Molecular Orbital diagrams bond orders of homonuclear and heteronuclear diatomic molecules and, ions(Ns, O2,Cy Ba, F,CO, NOandtheirions),, , Unit Ill (Periodic Properties of Atoms (with reference to s & p-block)), Brief discussion, factors affecting and variation trends of following properties in groups and periods. Effective nuclear charge, shielding, , (F screening effect, Slater rules, Atomic and onic radi, Electronegativty, Pauling’s /Aliced Rochow’s scales, lonization enthalpy,, Electron gainenthalpy, , , , Unit IV (Recapitulation of Basics of Organic Chemistry), , Hybridization, bond lengths and bond angles, bond energy, localized and delocalized chemical bonding, Van der Waals interactions,, inclusion compounds, Clatherates, Charge transfer complexes, hyperconjugation, Dipole moment, Electronic Displacements, Inductive, electromeric, resonance mesomericeffectsand their applications, , Unit V (Mechanism of Organic Reactions), , Curved arrow notation, drawing electron movements with allows, half-headed and double-headed ar-ows, homolytic and heterolytic, ‘bond fission, Types of reagents electrophiles and nucleophiles, Types of organic reactions, Energy considerations. Reactive, Intermediates Carbocations, carbanions, free radicals, carbenes, arynes and nitrenes (with examples), , Unit VI (Steriochemistry), , ‘Concept f isomerism, Types of isomerism; Optical somerism elements of symmetry, molecular chirality, enantiomers, stereogenic, ‘enter, optical activity, properties of enantiomers, chiral and achiral molecules with two stereogenic centers, disasteromers, threo and, ‘erythro diastereomers, meso compounds, resolution of enantionmer, inversion, retention and recemization. Relative and absolute, «configuration, sequence rules, D & Land R & S systems of nomenclature. Geometric isomerism determination of configuration of, ‘Geometric isomers, E & Z system of nomenclature, geometric isomerism in oximes and alicyclic compounds. Conformational, 'somerism conformational analysis of ethane and n-butane; conformations of cyclohexane, axial and equatorial bonds, conformation, ‘of mono substituted cyclohexane derivatives, Newman projection and Sawhorse formulae, Fischer and fiying wedge formulae,, Difference between configuration and conformation, , Unit Vil (Basic Computer System (in brief), , Hardware and Software; Input devices, Storage devices, Output devices, Cental Processing Unit (Control Unit and Arithmetic Logic, , Unit; Number system (Binary, Octal and Hexadecimal Operating System); Computer Codes (BCD and ASCII), Numeric/String, , {itziants and varabes, Operating Systems (D05, WINDOWS, and Linux Introduction of Software languages: Low level and High, languages (Machine language, Assembly language; QBASIC, FORTRAN) Software Products (Office, chemsketch, sclab, matlab,, , ‘nyperchem, et.) intemet application,, , , , ‘Unit Vill (Mathematical Concepts for Chemistry), ‘Logarthmic relations, curve sketching linear graphs and calculation of slopes, cfferentation of functions like Kx, eX, sin x, og, ‘maxima nd minima, partial differentiation and reciprocity relations, Integration of some useflrelevant functions, permutations an, , , , meetin